MATERIAL SAFETY DATA SHEET
RESISTOCOAT HB PART A
Page: 1
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Section 2: Hazards identification
2.1. Classification of the substance or mixture
2.2. Label elements
Compilation date: 04/11/2014
Revision date: 13/06/2016
Revision No: 2
Product name: RESISTOCOAT HB PART A
Product code: AFF.005(A)
Use of substance / mixture: PC1: Adhesives, sealants. PC9a: Coatings and paints, thinners, paint removers.
Company name: AFF Epoxy Coatings Ltd
Unit 9 Thames Trading Centre Woodrow Way
Irlam, Manchester M44 6BP
United Kingdom
Tel: +44 (0) 161 478 2054
Email: info@epoxypaint.co.uk
Emergency tel: +44 (0) 7850 905 556
(office hours only)
Classification under CLP: Aquatic Chronic 2: H411; Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317
Most important adverse effects: Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Toxic to aquatic life with long lasting effects.
Label elements:
Hazard statements: H315: Causes skin irritation.
H317: May cause an allergic skin reaction. H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.
Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark
GHS09: Environmental
Precautionary statements: P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection. P302+350: IF ON SKIN: Gently wash with plenty of soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P502: Refer to manufacturer/supplier for information on recovery/recycling.
[cont…]
SAFETY DATA SHEET
RESISTOCOAT HB PART A
Page: 2
[cont…]
Section 3: Composition/information on ingredients
3.2. Mixtures
Section 4: First aid measures
4.1. Description of first aid measures
4.3. Indication of any immediate medical attention and special treatment needed
Section 5: Fire-fighting measures
PBT: This product is not identified as a PBT/vPvB substance.
Hazardous ingredients:
BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} – REACH registered number(s): 01-2119456619-26-####
EINECS
CAS
PBT / WEL
CLP Classification
Percent
500-033-5
25068-38-6

Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317; Aquatic Chronic 2: H411
20-30%
FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL – REACH registered number(s): 01-2119454392-40-####
500-006-8
9003-36-5

Skin Irrit. 2: H315; Skin Sens. 1: H317; Aquatic Chronic 2: H411
10-20%
OXIRANE, MONO[(C12-14ALKYLOXY)METHYL] DERIVATIVES – REACH registered number(s): 01-2119485289-22-#### BENZYL ALCOHOL – REACH registered number(s): 01-2119492630-38-####
LOW BOILING POINT NAPHTHA – UNSPECIFIED – SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.
265-199-0
64742-95-6

Asp. Tox. 1: H304; Flam. Liq. 3: H226;
STOT SE 3: H335; Aquatic Chronic 2:
H411
<1% Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. Skin contact: There may be irritation and redness at the site of contact. An itchy rash may occur at the site of contact. There may be redness or whiteness of the skin in the area of exposure. Eye contact: There may be irritation and redness. The eyes may water profusely. There may be severe pain. There may be irritation and pain. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. Immediate / special treatment: Eye bathing equipment should be available on the premises. 4.2. Most important symptoms and effects, both acute and delayed 2.3. Other hazards 271-846-8 68609-97-2 - Skin Irrit. 2: H315; Skin Sens. 1: H317 3-10% 202-859-9 100-51-6 - Acute Tox. 4: H332; Acute Tox. 4: H302 <1% [cont...] SAFETY DATA SHEET RESISTOCOAT HB PART A Page: 3 5.3. Advice for fire-fighters 6.3. Methods and material for containment and cleaning up Section 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Section 8: Exposure controls/personal protection 8.1. Control parameters DNEL/PNEC Values Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers. Exposure hazards: In combustion emits toxic fumes. Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Reference to other sections: Refer to section 8 of SDS. Refer to section 13 of SDS. Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. The floor of the storage room must be impermeable to prevent the escape of liquids. Suitable packaging: Must only be kept in original packaging. Specific end use(s): No data available. Workplace exposure limits: No data available. Hazardous ingredients: 6.4. Reference to other sections 6.2. Environmental precautions 6.1. Personal precautions, protective equipment and emergency procedures Section 6: Accidental release measures 5.2. Special hazards arising from the substance or mixture 5.1. Extinguishing media [cont...] SAFETY DATA SHEET RESISTOCOAT HB PART A Page: 4 BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} Type Exposure Value Population Effect DNEL Inhalation (Short & Long Term) 12.25 mg/m³ Workers Systemic DNEL Dermal (Short & Long Term) 8.33 mg/kg bw/day Workers Systemic DNEL Dermal (Short & Long Term) 3.571 mg/kg bw/day General Population Systemic DNEL Oral 0.75 mg/kg bw/day General Population Systemic PNEC Fresh water 0.006 mg/L - - PNEC Marine water 0.0006 mg/L - - PNEC Fresh water sediments 0.996 mg/kg sediment - - PNEC Marine sediments 0.0996 mg/kg sedimen - - PNEC Soil (agricultural) 0.196 mg/kg soil dw - - FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL Type Exposure Value Population Effect DNEL Inhalation (repeated dose) 29.39 mg/m³ Workers Systemic DNEL Dermal (repeated dose) 104.15 mg/kg bw/day Workers Systemic DNEL Inhalation (repeated dose) 8.7 mg/m³ General Population Systemic DNEL Dermal (repeated dose) 62.5 mg/kg bw/day General Population Systemic DNEL Oral (repeated dose) 6.25 mg/kg bw/day General Population Systemic PNEC Fresh water 0.003 mg/L - - PNEC Marine water 0.0003 mg/L - - PNEC Fresh water sediments 0.294 mg/kg sediment - - PNEC Marine sediments 0.0294 mg/kg sedimen - - PNEC Soil (agricultural) 0.237 mg/kg soil dw - - OXIRANE, MONO[(C12-14ALKYLOXY)METHYL] DERIVATIVES Type Exposure Value Population Effect DNEL Inhalation (repeated dose) 3.6 mg/m³ Workers - DNEL Dermal (repeated dose) 1 mg/kg bw/day Workers - DNEL Inhalation (repeated dose) 0.87 mg/m³ General Population - DNEL Dermal (repeated dose) 0.5 mg/kg bw/day General Population - DNEL Oral (repeated dose) 0.5 mg/kg bw/day General Population - PNEC Fresh water 0.0072 mg/L - - PNEC Marine water 0.00072 mg/L - - PNEC Fresh water sediments 307.16 mg/kg sedimen - - PNEC Marine sediments 30.72 mg/kg sediment - - PNEC Soil (agricultural) 61.42 mg/kg soil dw - - BENZYL ALCOHOL Type Exposure Value Population Effect DNEL Inhalation (repeated dose) 22 mg/m³ Workers Systemic DNEL Inhalation (repeated dose, Acute) 110 mg/m³ Workers Systemic DNEL Dermal (repeated dose) 8 mg/kg bw/day Workers Systemic DNEL Dermal (repeated dose, Acute) 40 mg/kg bw/day Workers Systemic DNEL Inhalation (repeated dose) 5.4 mg/m³ Workers Systemic [cont...] SAFETY DATA SHEET RESISTOCOAT HB PART A Page: 5 8.2. Exposure controls 9.2. Other information Section 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability DNEL Inhalation (repeated dose, Acute) 27 mg/m³ Workers Systemic DNEL Dermal (repeated dose) 4 mg/kg bw/day General Population Systemic DNEL Dermal (repeated dose, Acute) 20 mg/kg bw/day General Population Systemic DNEL Oral (repeated dose) 4 mg/kg bw/day General Population Systemic DNEL Oral (repeated dose, Acute) 20 mg/kg bw/day General Population Systemic PNEC Fresh water 1 mg/L - - PNEC Marine water 0.1 mg/L - - PNEC Fresh water sediments 5.27 mg/kg sediment - - PNEC Marine sediments 0.527 mg/kg sediment - - Engineering measures: Ensure there is sufficient ventilation of the area. The floor of the storage room must be impermeable to prevent the escape of liquids. Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Hand protection: Protective gloves. Breakthrough time of the glove material > 2 hours. BS EN 374:2003
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Environmental: Refer to specific Member State legislation for requirements under Community environmental legislation.
State: Liquid
Colour: Various
Odour: Characteristic odour
Evaporation rate: Slow
Oxidising: Non-oxidising (by EC criteria)
Solubility in water: No data available.
Also soluble in: Most organic solvents.
Viscosity: Viscous
Boiling point/range°C: > 300 Melting point/range°C: No data available. Flammability limits %: lower: No data available. upper: No data available. Flash point°C: > 150 Part.coeff. n-octanol/water: No data available.
Autoflammability°C: > 400 Vapour pressure: < 0.0001 mmHg Relative density: 1.5 - 2.0 pH: Approx. 7 VOC g/l: No data available. Other information: Not applicable. Reactivity: Stable under recommended transport or storage conditions. Chemical stability: Stable under normal conditions. 9.1. Information on basic physical and chemical properties Section 9: Physical and chemical properties [cont...] SAFETY DATA SHEET RESISTOCOAT HB PART A Page: 6 Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. Conditions to avoid: Heat. Materials to avoid: Strong oxidising agents. Strong acids. Haz. decomp. products: In combustion emits toxic fumes. Hazardous ingredients: BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} ORL MUS LD50 15600 mg/kg ORL RAT LD50 11400 mg/kg SKN RBT LD50 >20
ml/kg
OXIRANE, MONO[(C12-14ALKYLOXY)METHYL] DERIVATIVES
ORL
RAT
LD50
17100
mg/kg
BENZYL ALCOHOL
IVN
RAT
LD50
53
mg/kg
ORL
MUS
LD50
1360
mg/kg
ORL
RAT
LD50
1230
mg/kg
LOW BOILING POINT NAPHTHA – UNSPECIFIED – SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.
ORL
RAT
LD50
8400
mg/kg
Relevant hazards for substance:
Hazard
Route
Basis
Skin corrosion/irritation
DRM
Hazardous: calculated
Serious eye damage/irritation
OPT
Hazardous: calculated
Respiratory/skin sensitisation
DRM
Hazardous: calculated
Skin contact: There may be irritation and redness at the site of contact. An itchy rash may occur at the site of contact. There may be redness or whiteness of the skin in the area of exposure.
Eye contact: There may be irritation and redness. The eyes may water profusely. There may be severe
pain. There may be irritation and pain.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Other information: Not applicable.
10.4. Conditions to avoid
10.3. Possibility of hazardous reactions
10.5. Incompatible materials
10.6. Hazardous decomposition products
Section 11: Toxicological information
11.1. Information on toxicological effects
Symptoms / routes of exposure
[cont…]
SAFETY DATA SHEET
RESISTOCOAT HB PART A
Page: 7
Ecotoxicity values: No data available.
Persistence and degradability: Not biodegradable.
Bioaccumulative potential: Bioaccumulation potential.
Mobility: Readily absorbed into soil.
PBT identification: This product is not identified as a PBT/vPvB substance.
Other adverse effects: Toxic to aquatic organisms. Toxic to soil organisms.
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. Physico-chemical treatment not specified elsewhere in this Annex which results in final compounds or mixtures which are discarded by means of any of the other possible disposal operations (e.g. evaporation, drying, calcination, etc.).
Recovery operations: Not applicable.
Waste code number: 08 02 99
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.
UN number: UN3082
Shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT}; FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL)
Transport class: 9
Packing group: III
Environmentally hazardous: Yes Marine pollutant: No
Special precautions: No special precautions.
14.3. Transport hazard class(es)
14.1. UN number
Section 14: Transport information
Section 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
Section 13: Disposal considerations
13.1. Waste treatment methods
14.2. UN proper shipping name
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
SAFETY DATA SHEET
RESISTOCOAT HB PART A
Page: 8
[final page]
Tunnel code: E
Transport category: 3
Specific regulations: This product is a Seveso category/named substance in Annex I of Council Directive 96/82/EC. This product is or contains a a dangerous chemical for export or import according to Regulation (EC) No 689/2008.
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.
H317: May cause an allergic skin reaction. H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.
Other information
Section 16: Other information
15.2. Chemical Safety Assessment
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture